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Surface-Engineered Cationic Nanocrystals Stable in 3D Coat v4.9.05 Crack Full Version 2019 Free Download [Fixed] Buffers and High Ionic Strength Solutions

Conclusions


In summary, we have developed a 3D Coat v4.9.05 Crack Full Version 2019 Free Download [Fixed] of small (<2.5 nm) cationic ligands that confer colloidal stability in aqueous solution for various NCs. The coordinating group of these ligands was chosen on the basis of compatibility with the NC surface in accordance with the principles of hard–soft acid–base theory. Guanidium and quaternary amine groups, 3D Coat v4.9.05 Crack Full Version 2019 Free Download [Fixed] retain their charge at high pH, were used to impart positive surface charge to the newly functionalized NCs. The generality of this approach was confirmed for a variety of NCs, including semiconductor, magnetic, and plasmonic materials of various shapes and ranging in size from 1.5 to 20 nm. Small (<12 nm) cationic NCs proved stable for months in water and for days to months, depending on NC/ligand pair, in buffer and salt solutions. Larger NCs, including 13 × 49 nm Au nanorods, showed short-term colloidal stability in some of the tested buffer solutions but are stable for months in water and several polar organic solvents.

The stability of these NCs in high ionic strength solutions and their positive surface charge allowed us to explore two possible applications. First, cationic NCs were found to be potentially useful as selective staining agents for cell imaging with characteristics that depend on the ligand layer composition. Second, combining highly stable cationic and anionic NCs yielded nanocrystalline solids with controllable and uniform 2D and 3D distributions of two distinct types of NCs. Engineering of such nanocrystalline solids is of interest for thermoelectric and photovoltaic applications, where highly uniform distributions of component NCs possessing different functionalities is appealing.

Supporting Information


The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.7b03504.

  • Materials and details of NCs and peptide ligands syntheses; FTIR, SEM, and AFM images; cellular imaging with neutral QDs (PDF)

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Author Information


    • Maksym V. Kovalenko- Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland;  Laboratory for Thin Films and Photovoltaics, Empa-Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dübendorf, Switzerland;  Orcidhttp://orcid.org/0000-0002-6396-8938;  Email: [email protected]
    • Ryan M. Dragoman - Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

    • Marcel Grogg - Laboratory of Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

    • Maryna I. Bodnarchuk - Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland;  Laboratory for Thin Films and Photovoltaics, Empa-Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dübendorf, Switzerland

    • Peter Tiefenboeck - Institute of Pharmaceutical Sciences, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

    • Donald Hilvert - Laboratory of Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

  • All authors have given approval to the final version of the manuscript.

  • The authors declare no 3D Coat v4.9.05 Crack Full Version 2019 Free Download [Fixed] financial interest.

Acknowledgment


We acknowledge financial support from the European Union through the FP7 (ERC Starting Grant NANOSOLID, GA No. 306733; Marie Curie Fellowship IIF-GA-2012-330524), the Swiss National Science Foundation (SNF Ambizione Energy grant, Grant No. PZENP2_154287), and the ETH Zurich. We would like to thank Dr. Marc Walter for the SEM images and Matthias J. Grotevent for the AFM measurements. We are also grateful to Professor J.-C. Leroux for the use of the fluorescence microscope in his lab.

This article references 99 other publications.

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    Advanced Materials (Weinheim, Germany) (2009), 21 (21), 2133-2148CODEN: ADVMEW; wps office 2021 crack ISSN:0935-9648. (Wiley-VCH Verlag GmbH & Co. KGaA)

    A review. Various inorg. nanoparticles were used as magnetic resonance imaging (MRI) contrast agents due to their unique properties, such as large surface area and efficient contrasting effect. Since the first use of superparamagnetic iron oxide (SPIO) as a liver contrast agent, nanoparticulate MRI contrast agents have attracted a lot of attention. Magnetic iron oxide nanoparticles were extensively used as MRI contrast agents due to their ability to shorten T2* relaxation times in the liver, spleen, and bone marrow. More recently, uniform ferrite nanoparticles with high crystallinity were successfully employed as new T2 MRI contrast agents with improved relaxation properties. Iron oxide nanoparticles functionalized with targeting agents were used for targeted imaging via the site-specific accumulation of nanoparticles at the targets of interest. Recently, extensive research was conducted to develop nanoparticle-based T1 contrast agents to overcome the drawbacks of iron oxide pdf to image software - Crack Key For U neg. T2 contrast agents. In this report, the authors summarize the recent progress in inorg. nanoparticle-based MRI contrast agents.

    >> More from SciFinder ®

    https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADC%252BD1MXntVGqu78%253D&md5=8cc7c7ed8b0df3e196c893a5e37cd228
  2. 2

    Kamat, P. V.Quantum Dot Solar Cells. The Next Big Thing in Photovoltaics

Источник: https://pubs.acs.org/doi/10.1021/acs.chemmater.7b03504

Most searched keywords

Let’s first take a look at what are the most popular keywords that customers have been using when searching for icons on Iconfinder. The table below lists these keywords in order of popularity, from most searched to least.

The column called Supply-Demand ratio shows how competitive the Iconfinder market for that keyword is:

  • A ratio lower than 1 means that there is space for more icons.
  • A ratio higher than 1 means that the market is very competitive — there are more icons than searches for that keyword, so sales are not guaranteed.

The last column shows whether the searches for that keyword have been increasing or decreasing as compared to the same period last year.

It is not surprising to see keywords such as “arrow”, “phone”, “download”, “search” or “user” ranking as the most searched in 2019 so far. These are the basis of UIs and websites and most customers will be looking for these. They are a good place to start if you are new at icon design.

As an icon designer, you are probably asking what are the icons that customers buy together. This is useful information when deciding what icons to include in the same set or the same icon family. To answer this question, we looked at what keywords customers search for successively.

For example, a typical case is to search for “facebook” and then right afterward search for “twitter”. Depending on how many times this exact combination of searches happened, we can intuit how likely it is for a customer to buy the two icons together. Another example of 3D Coat v4.9.05 Crack Full Version 2019 Free Download [Fixed] kind could be a search for “arrow up”, followed by a new search for “arrow down”.

The table below lists the keyword combinations used to search on Iconfinder, from most to least popular. The first keyword is the one that the customer used in the first search. The second keyword is the one the customer used in the second search, immediately after the first one. Most cases are complementary keywords.

This list should be taken with caution, however, as some examples could be interpreted differently. Sometimes, the customer might make a typo and then search for the correct word in the second search. For example, a typo such as “cofee” in the first search would be followed by a second search with the correct spelling of the word: “coffee”.

Synonym keywords — a hint for better tagging

Another very important scenario is when customers cannot find what they are looking for with the first keyword and then try with a second one. This corresponds to words that are synonyms. For example, if you cannot find the right icon using the keyword “remove”, you might try using the word “delete” instead. These are important clues for tagging — they should help you come up with better tags.

Knowing that there were 791 times when people searched for “remove” and then, immediately after, searched for “delete” tells you that those are two very important tags to add to your relevant icons. This way, you help the customers find your icons more easily.

If you need help finding synonyms when tagging, a good idea is to use an external tool such as this one: https://www.powerthesaurus.org/. When uploading icons to Iconfinder, our tagging tool also suggests other tags based on what you enter. Note that the recommended number of tags is between 4 and 7 per icon. Read Iconfinder’s guidelines for tagging.

The process of tagging

Tagging icons is the most important thing that you as a designer can do for your business. It should be an integral part of your design process. It is equally important to get the tags right as it is to create good quality icons.

After you have decided on what the right tags are — hopefully also with the help of our tips above — you need to do tagging in a systematic manner. Read about this in our tutorial How to use artboards export to auto-tag icons.

We looked at what keywords gain popularity in Q4 by looking at the searches in October, November, and December last year. We compared those to the previous 3 months and selected only the keywords that had 3D Coat v4.9.05 Crack Full Version 2019 Free Download [Fixed] large increase in searches.

We noticed mostly searches related to the main festivities during fall and winter: Halloween, Thanksgiving, Christmas, New Year and Diwali. The chart below shows at which time of the year the searches for each type of keyword reach a peak. For a complete list of keywords and their increase in popularity, check the Seasonal trends for keywords in Q4.

Searches per week and month for different keywords in Q4 2018.

Here are some of the seasonal sets that we consider as high quality, which can hopefully inspire you.

For more ideas on what icons to create and when keep an eye on Google Trends. It is a good source of popular topics that people are presently searching for online and a good indicator of what customers are searching for on Iconfinder too.

Here are the campaigns we plan to run in Q4, for which we often promote icons that match the theme of the campaign. We recommend designers to upload the themed icons before the campaign begins, in order to have a chance to be featured.

Here is an example of the Halloween campaign (which is running until the end of October) where we offer discounts on the Iconfider Pro plans. For this campaign, we featured beautifully-drawn Halloween icon sets.

The list below shows the category-style combinations in order of sales, from most sales to least. The best-sellers are Business & Finance in outline, glyph, and flat styles, followed by Avatars & Smileys in flat style, and UI in outline style.

You should pay attention to the last column (Supply-Demand ratio), which shows how saturated the market is in each category-style pair.

  • A ratio lower than 1 means that there is space for more icons.
  • A ratio higher than 1 means that the market is very competitive — there are more icons than searches for that keyword, so sales are not guaranteed.

Note that these category-style pairs are very competitive, so it is important to try to stand out from the crowd and differentiate yourself.

To make this list easier to grasp, we’ve added a few examples of sets that correspond to the category-style pairs from the top of the list.

From the list above, we have selected only those category-style combinations that offer opportunities to add more icons. These are the ones with a supply-demand ratio lower than 1, which means that they sell more icons than the total number of icons available on Iconfinder.

Pay attention, however, to the number of icons sold in each category-style pair. These are not among the top seller ones, which means that you cannot expect that many sales. Yet, creating icons for these is a good idea because there is less competition.

To illustrate what the list means, we are adding a few examples of good sets for the first few category-style pairs.

Here we are listing a few examples of what we consider as bad practices when it comes to designing icons. We take the point of view of the customer by thinking in terms of the usability of the icon.

Directly-converted glyphs

Over the last few months, we have noticed an increase in the popularity of a certain style of glyph icons. It is the practice of creating an outline icon and then inverting it so that it looks like a glyph.

This is an example of what we mean by glyph icons that have been directly converted from their outline versions:

As you can see in the example above, the icons become very difficult 3D Coat v4.9.05 Crack Full Version 2019 Free Download [Fixed] recognize, especially in small sizes. Icons are meant to be used in small sizes, so simply creating a style conversion, without reinterpreting the icons, makes them lose their entire functionality.

Let’s look at a few examples together.

Bad glyph icons (directly-converted)

In all these examples, the designer made a direct style conversion, mostly because it only takes a second to do. However, the icons do not look good and Iconfinder does not accept them anymore.

When designing a glyph icon, the icon needs to be rethought based on the style limitations, making sure that they are easy to understand. Glyph icons are characterized by the use of negative space.

Good glyph icons

In the examples below, the icons are not simply converted directly to glyph. Instead, the designer has paid attention that the concept that the icon represents is still very clear.

Gradients in outline icons

We also noticed a trend of gradients in outline icons. In general, using colors in outline icons needs to be very well thought out. Colors need to play a role in the icon, like highlighting the important parts of the icon itself.

You might think that adding a gradient to an outline icon makes it cool and appealing. In reality, customers will have more trouble if they want to change the color of the icon, as gradients are not so easy to manage, especially for customers with no graphic design knowledge.

In the example below, using a 3-color gradient is definitely not going to make the icons more appealing. Instead, the icons lose their usability, as very few or no customers will want to buy them. Usually, customers look for icons that fit a certain color scheme (their brand’s colors, for instance) and these icons would bring more work for the customers when trying to change the colors.

Remember to always keep the customer in mind when designing icons. We recommend staying away from bad practices — such as directly-converted glyphs and gradients in outline icons — that can ultimately hurt sales.

We hope this report will help you identify the opportunities in the icon market and will inspire you to create beautiful icons.

This report is part of a series that are released every quarter. It crunches data on supply and demand on the Iconfinder marketplace, hoping to lead designers to create the right icons.

Drop us a message at support@iconfinder.com if you have any questions or feedback.

Are you interested in becoming a contributor on Iconfinder? This is the place to start: How to sell icons on Iconfinder

Источник: https://blog.iconfinder.com/iconfinder-designer-report-q4-2019-99c3e5fba587

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Surface-Engineered Cationic Nanocrystals Stable in Biological Buffers and High Ionic Strength Solutions

Conclusions


In summary, we have developed a collection of small (<2.5 nm) cationic ligands that confer colloidal stability in aqueous solution for various NCs. The coordinating group of these ligands was chosen on the basis of compatibility with the NC surface in accordance with the principles of hard–soft acid–base theory. Guanidium and quaternary amine groups, which retain their charge at high pH, were used to impart positive surface charge to the newly functionalized NCs. The generality of this approach was confirmed for a variety of NCs, including semiconductor, magnetic, and plasmonic materials of various shapes and ranging in size from 1.5 to 20 nm. Small (<12 nm) cationic NCs proved stable for months in water and for days to months, depending on NC/ligand pair, in buffer and salt solutions. Larger NCs, including 13 × 49 nm Au nanorods, showed short-term colloidal stability in some of the tested buffer solutions but are stable for months in water and several polar organic solvents.

The stability of these NCs in high ionic strength solutions and their positive surface charge allowed us to explore two possible applications. First, cationic NCs were found to be potentially useful as selective staining agents for cell imaging with characteristics that depend on the ligand layer composition. Second, combining highly stable cationic and anionic NCs yielded nanocrystalline solids with controllable and uniform 2D and 3D distributions of two distinct types of NCs. Engineering of such nanocrystalline solids is of interest for thermoelectric and photovoltaic applications, where highly uniform distributions of component NCs possessing different functionalities is appealing.

Supporting Information


The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.7b03504.

  • Materials and details of NCs and peptide ligands syntheses; FTIR, SEM, and AFM images; cellular imaging with neutral QDs (PDF)

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Author Information


    • Maksym V. Kovalenko- Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland;  Laboratory for Thin Films and Photovoltaics, Empa-Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dübendorf, Switzerland;  Orcidhttp://orcid.org/0000-0002-6396-8938;  Email: [email protected]
    • Ryan M. Dragoman - Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

    • Marcel Grogg - Laboratory of Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

    • Maryna I. Bodnarchuk - Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland;  Laboratory for Thin Films and Photovoltaics, Empa-Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dübendorf, Switzerland

    • Peter Tiefenboeck - Institute of Pharmaceutical Sciences, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

    • Donald Hilvert - Laboratory of Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

  • All authors have given approval to the final version of the manuscript.

  • The authors declare no competing financial interest.

Acknowledgment


We acknowledge financial support from the European Union through the FP7 (ERC Starting Grant NANOSOLID, GA No. 306733; Marie Curie Fellowship IIF-GA-2012-330524), the Swiss National Science Foundation (SNF Ambizione Energy grant, Grant No. PZENP2_154287), and the ETH Zurich. We would like to thank Dr. Marc Walter for the SEM images and Matthias J. Grotevent for the AFM measurements. We are also grateful to Professor J.-C. Leroux for the use of the fluorescence microscope in his lab.

This article references 99 other publications.

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    Inorganic Nanoparticles for MRI Contrast Agents

    Na, Hyon Bin; Song, In Chan; Hyeon, Taeghwan

    Advanced Materials (Weinheim, Germany) (2009), 21 (21), 2133-2148CODEN: ADVMEW; ISSN:0935-9648. (Wiley-VCH Verlag GmbH & Co. KGaA)

    A review. Various inorg. nanoparticles were used as magnetic resonance imaging (MRI) contrast agents due to their unique properties, such as large surface area and efficient contrasting effect. Since the first use of superparamagnetic iron oxide (SPIO) as a liver contrast agent, nanoparticulate MRI contrast agents have attracted a lot of attention. Magnetic iron oxide nanoparticles were extensively used as MRI contrast agents due to their ability to shorten T2* relaxation times in the liver, spleen, and bone marrow. More recently, uniform ferrite nanoparticles with high crystallinity were successfully employed as new T2 MRI contrast agents with improved relaxation properties. Iron oxide nanoparticles functionalized with targeting agents were used for targeted imaging via the site-specific accumulation of nanoparticles at the targets of interest. Recently, extensive research was conducted to develop nanoparticle-based T1 contrast agents to overcome the drawbacks of iron oxide nanoparticle-based neg. T2 contrast agents. In this report, the authors summarize the recent progress in inorg. nanoparticle-based MRI contrast agents.

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    https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADC%252BD1MXntVGqu78%253D&md5=8cc7c7ed8b0df3e196c893a5e37cd228
  2. 2

    Kamat, P. V.Quantum Dot Solar Cells. The Next Big Thing in Photovoltaics

Источник: https://pubs.acs.org/doi/10.1021/acs.chemmater.7b03504

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Most searched keywords

Let’s first take a look at what are the most popular keywords that customers have been using when searching for icons on Iconfinder. The table below lists these keywords in order of popularity, from most searched to least.

The column called Supply-Demand ratio shows how competitive the Iconfinder market for that keyword is:

  • A ratio lower than 1 means that there is space for more icons.
  • A ratio higher than 1 means that the market is very competitive — there are more icons than searches for that keyword, so sales are not guaranteed.

The last column shows whether the searches for that keyword have been increasing or decreasing as compared to the same period last year.

It is not surprising to see keywords such as “arrow”, “phone”, “download”, “search” or “user” ranking as the most searched in 2019 so far. These are the basis of UIs and websites and most customers will be looking for these. They are a good place to start if you are new at icon design.

As an icon designer, you are probably asking what are the icons that customers buy together. This is useful information when deciding what icons to include in the same set or the same icon family. To answer this question, we looked at what keywords customers search for successively.

For example, a typical case is to search for “facebook” and then right afterward search for “twitter”. Depending on how many times this exact combination of searches happened, we can intuit how likely it is for a customer to buy the two icons together. Another example of this kind could be a search for “arrow up”, followed by a new search for “arrow down”.

The table below lists the keyword combinations used to search on Iconfinder, from most to least popular. The first keyword is the one that the customer used in the first search. The second keyword is the one the customer used in the second search, immediately after the first one. Most cases are complementary keywords.

This list should be taken with caution, however, as some examples could be interpreted differently. Sometimes, the customer might make a typo and then search for the correct word in the second search. For example, a typo such as “cofee” in the first search would be followed by a second search with the correct spelling of the word: “coffee”.

Synonym keywords — a hint for better tagging

Another very important scenario is when customers cannot find what they are looking for with the first keyword and then try with a second one. This corresponds to words that are synonyms. For example, if you cannot find the right icon using the keyword “remove”, you might try using the word “delete” instead. These are important clues for tagging — they should help you come up with better tags.

Knowing that there were 791 times when people searched for “remove” and then, immediately after, searched for “delete” tells you that those are two very important tags to add to your relevant icons. This way, you help the customers find your icons more easily.

If you need help finding synonyms when tagging, a good idea is to use an external tool such as this one: https://www.powerthesaurus.org/. When uploading icons to Iconfinder, our tagging tool also suggests other tags based on what you enter. Note that the recommended number of tags is between 4 and 7 per icon. Read Iconfinder’s guidelines for tagging.

The process of tagging

Tagging icons is the most important thing that you as a designer can do for your business. It should be an integral part of your design process. It is equally important to get the tags right as it is to create good quality icons.

After you have decided on what the right tags are — hopefully also with the help of our tips above — you need to do tagging in a systematic manner. Read about this in our tutorial How to use artboards export to auto-tag icons.

We looked at what keywords gain popularity in Q4 by looking at the searches in October, November, and December last year. We compared those to the previous 3 months and selected only the keywords that had a large increase in searches.

We noticed mostly searches related to the main festivities during fall and winter: Halloween, Thanksgiving, Christmas, New Year and Diwali. The chart below shows at which time of the year the searches for each type of keyword reach a peak. For a complete list of keywords and their increase in popularity, check the Seasonal trends for keywords in Q4.

Searches per week and month for different keywords in Q4 2018.

Here are some of the seasonal sets that we consider as high quality, which can hopefully inspire you.

For more ideas on what icons to create and when keep an eye on Google Trends. It is a good source of popular topics that people are presently searching for online and a good indicator of what customers are searching for on Iconfinder too.

Here are the campaigns we plan to run in Q4, for which we often promote icons that match the theme of the campaign. We recommend designers to upload the themed icons before the campaign begins, in order to have a chance to be featured.

Here is an example of the Halloween campaign (which is running until the end of October) where we offer discounts on the Iconfider Pro plans. For this campaign, we featured beautifully-drawn Halloween icon sets.

The list below shows the category-style combinations in order of sales, from most sales to least. The best-sellers are Business & Finance in outline, glyph, and flat styles, followed by Avatars & Smileys in flat style, and UI in outline style.

You should pay attention to the last column (Supply-Demand ratio), which shows how saturated the market is in each category-style pair.

  • A ratio lower than 1 means that there is space for more icons.
  • A ratio higher than 1 means that the market is very competitive — there are more icons than searches for that keyword, so sales are not guaranteed.

Note that these category-style pairs are very competitive, so it is important to try to stand out from the crowd and differentiate yourself.

To make this list easier to grasp, we’ve added a few examples of sets that correspond to the category-style pairs from the top of the list.

From the list above, we have selected only those category-style combinations that offer opportunities to add more icons. These are the ones with a supply-demand ratio lower than 1, which means that they sell more icons than the total number of icons available on Iconfinder.

Pay attention, however, to the number of icons sold in each category-style pair. These are not among the top seller ones, which means that you cannot expect that many sales. Yet, creating icons for these is a good idea because there is less competition.

To illustrate what the list means, we are adding a few examples of good sets for the first few category-style pairs.

Here we are listing a few examples of what we consider as bad practices when it comes to designing icons. We take the point of view of the customer by thinking in terms of the usability of the icon.

Directly-converted glyphs

Over the last few months, we have noticed an increase in the popularity of a certain style of glyph icons. It is the practice of creating an outline icon and then inverting it so that it looks like a glyph.

This is an example of what we mean by glyph icons that have been directly converted from their outline versions:

As you can see in the example above, the icons become very difficult to recognize, especially in small sizes. Icons are meant to be used in small sizes, so simply creating a style conversion, without reinterpreting the icons, makes them lose their entire functionality.

Let’s look at a few examples together.

Bad glyph icons (directly-converted)

In all these examples, the designer made a direct style conversion, mostly because it only takes a second to do. However, the icons do not look good and Iconfinder does not accept them anymore.

When designing a glyph icon, the icon needs to be rethought based on the style limitations, making sure that they are easy to understand. Glyph icons are characterized by the use of negative space.

Good glyph icons

In the examples below, the icons are not simply converted directly to glyph. Instead, the designer has paid attention that the concept that the icon represents is still very clear.

Gradients in outline icons

We also noticed a trend of gradients in outline icons. In general, using colors in outline icons needs to be very well thought out. Colors need to play a role in the icon, like highlighting the important parts of the icon itself.

You might think that adding a gradient to an outline icon makes it cool and appealing. In reality, customers will have more trouble if they want to change the color of the icon, as gradients are not so easy to manage, especially for customers with no graphic design knowledge.

In the example below, using a 3-color gradient is definitely not going to make the icons more appealing. Instead, the icons lose their usability, as very few or no customers will want to buy them. Usually, customers look for icons that fit a certain color scheme (their brand’s colors, for instance) and these icons would bring more work for the customers when trying to change the colors.

Remember to always keep the customer in mind when designing icons. We recommend staying away from bad practices — such as directly-converted glyphs and gradients in outline icons — that can ultimately hurt sales.

We hope this report will help you identify the opportunities in the icon market and will inspire you to create beautiful icons.

This report is part of a series that are released every quarter. It crunches data on supply and demand on the Iconfinder marketplace, hoping to lead designers to create the right icons.

Drop us a message at support@iconfinder.com if you have any questions or feedback.

Are you interested in becoming a contributor on Iconfinder? This is the place to start: How to sell icons on Iconfinder

Источник: https://blog.iconfinder.com/iconfinder-designer-report-q4-2019-99c3e5fba587
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Surface-Engineered Cationic Nanocrystals Stable in Biological Buffers and High Ionic Strength Solutions

Conclusions


In summary, we have developed a collection of small (<2.5 nm) cationic ligands that confer colloidal stability in aqueous solution for various NCs. The coordinating group of these ligands was chosen on the basis of compatibility with the NC surface in accordance with the principles of hard–soft acid–base theory. Guanidium and quaternary amine groups, which retain their charge at high pH, were used to impart positive surface charge to the newly functionalized NCs. The generality of this approach was confirmed for a variety of NCs, including semiconductor, magnetic, and plasmonic materials of various shapes and ranging in size from 1.5 to 20 nm. Small (<12 nm) cationic NCs proved stable for months in water and for days to months, depending on NC/ligand pair, in buffer and salt solutions. Larger NCs, including 13 × 49 nm Au nanorods, showed short-term colloidal stability in some of the tested buffer solutions but are stable for months in water and several polar organic solvents.

The stability of these NCs in high ionic strength solutions and their positive surface charge allowed us to explore two possible applications. First, cationic NCs were found to be potentially useful as selective staining agents for cell imaging with characteristics that depend on the ligand layer composition. Second, combining highly stable cationic and anionic NCs yielded nanocrystalline solids with controllable and uniform 2D and 3D distributions of two distinct types of NCs. Engineering of such nanocrystalline solids is of interest for thermoelectric and photovoltaic applications, where highly uniform distributions of component NCs possessing different functionalities is appealing.

Supporting Information


The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.7b03504.

  • Materials and details of NCs and peptide ligands syntheses; FTIR, SEM, and AFM images; cellular imaging with neutral QDs (PDF)

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Author Information


    • Maksym V. Kovalenko- Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland;  Laboratory for Thin Films and Photovoltaics, Empa-Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dübendorf, Switzerland;  Orcidhttp://orcid.org/0000-0002-6396-8938;  Email: [email protected]
    • Ryan M. Dragoman - Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

    • Marcel Grogg - Laboratory of Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

    • Maryna I. Bodnarchuk - Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland;  Laboratory for Thin Films and Photovoltaics, Empa-Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dübendorf, Switzerland

    • Peter Tiefenboeck - Institute of Pharmaceutical Sciences, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

    • Donald Hilvert - Laboratory of Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland

  • All authors have given approval to the final version of the manuscript.

  • The authors declare no competing financial interest.

Acknowledgment


We acknowledge financial support from the European Union through the FP7 (ERC Starting Grant NANOSOLID, GA No. 306733; Marie Curie Fellowship IIF-GA-2012-330524), the Swiss National Science Foundation (SNF Ambizione Energy grant, Grant No. PZENP2_154287), and the ETH Zurich. We would like to thank Dr. Marc Walter for the SEM images and Matthias J. Grotevent for the AFM measurements. We are also grateful to Professor J.-C. Leroux for the use of the fluorescence microscope in his lab.

This article references 99 other publications.

  1. 1
    Na, H. B.; Song, I. C.; Hyeon, T.Inorganic Nanoparticles for MRI Contrast AgentsAdv. Mater.2009, 21 (21) 2133–2148 DOI: 10.1002/adma.200802366
    [Crossref], [CAS], Google Scholar
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    Inorganic Nanoparticles for MRI Contrast Agents

    Na, Hyon Bin; Song, In Chan; Hyeon, Taeghwan

    Advanced Materials (Weinheim, Germany) (2009), 21 (21), 2133-2148CODEN: ADVMEW; ISSN:0935-9648. (Wiley-VCH Verlag GmbH & Co. KGaA)

    A review. Various inorg. nanoparticles were used as magnetic resonance imaging (MRI) contrast agents due to their unique properties, such as large surface area and efficient contrasting effect. Since the first use of superparamagnetic iron oxide (SPIO) as a liver contrast agent, nanoparticulate MRI contrast agents have attracted a lot of attention. Magnetic iron oxide nanoparticles were extensively used as MRI contrast agents due to their ability to shorten T2* relaxation times in the liver, spleen, and bone marrow. More recently, uniform ferrite nanoparticles with high crystallinity were successfully employed as new T2 MRI contrast agents with improved relaxation properties. Iron oxide nanoparticles functionalized with targeting agents were used for targeted imaging via the site-specific accumulation of nanoparticles at the targets of interest. Recently, extensive research was conducted to develop nanoparticle-based T1 contrast agents to overcome the drawbacks of iron oxide nanoparticle-based neg. T2 contrast agents. In this report, the authors summarize the recent progress in inorg. nanoparticle-based MRI contrast agents.

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    Kamat, P. V.Quantum Dot Solar Cells. The Next Big Thing in Photovoltaics

Источник: https://pubs.acs.org/doi/10.1021/acs.chemmater.7b03504

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Altium.Concord.Pro+MCAD.Plugins.v1.0.1.22 AMIQ DVT Eclipse IDE 19.1.13 Ansys.Additive.2019R2.2.Win64 Ansys.Discovery.Live.Ultimate.2019R2.Win64 Ansys.Electronics.2019R2.Win64 Ansys.Motion.2019R2.Win64 Ansys.OptiSLang.7.3.1.53589 Ansys.Products.2019R2.Win64 Antenna Magus 2019.2 v9.2 x64 AnyBody Modeling System 7.2 x64 Applications.in.CADD.n4ce.Designer.v4.10d AspenTech aspenONE Suite 11.0 Audytor SET 7.1 Avenza.Geographic.Imager.for.Adobe.Photoshop.5.4 BAE ShipWeight Enterprise 13.0 x64 Bentley SewerGEMS CONNECT Edition Update 2 v10.02.01.04 BioSolveIT.SeeSAR.6.1 Cadence XCELIUMMAIN v18.03.001 Linux CAE Datamine NPV Scheduler v4.30.55.0 CAESES.FRIENDSHIP-Framework.4.4.2 Camnetics Suite 2019 9CD Canadian.Wood.Council.WoodWorks.Design.Office.USA.Edition.v11.1.SR-1 CAXperts.S3D2PDS.v1.1.1702.202 CCG Molecular.Operating.Environment(MOE).V2015.10 Cedrat Motor-CAD v12.1.7 CGERisk BowTieXP 9.2.11 Chasm Consulting VentSim Premium Design 5.1.4.3 Chemstations.CHEMCAD.Suite.v7.1.5.11490 Chief.Architect.Home.Designer.Professional.2020.v21.1.1.2 CIMCO Machine Simulation v8.06.03 Circle.Cardiovascular.Imaging.CVI42.v5.1.1 CLC Genomics Workbench 12.0 Win/Linux COMSOL.Multiphysics.5.4.0.346.Full.Win64.&.Linux64 Concept GateVision 6.10.5 Win/Linux Concept RTLvision 6.10.5 Win/Linux Concept SpiceVision 6.10.5 Win/Linux Concept StarVision 6.10.5 Win/Linux Concepts.NREC.Suite.8.7.X(AXCENT64,AXIAL,COMPAL,FANPAL,PUMPAL,RITAL) Converge.2.4.19 CSI SAP2000 Ultimate 21.0 CSoft.RasterDesk.Pro.v17.0.3019.for.AutoCAD2010-2018 CSoft.Spotlight.Pro.v17.0.1458 Dassault.Systemes.DraftSight.2019.SP0.Win64 DATAKIT.CrossManager.2019.2.build.2019-04-16.Win64 DATAKIT.SolidWorks.Plugins.2019.2.build.2019-04-16.Win64 Datamine Discover 2019/2017 x64 Datamine.Studio.UG.v2.1.40.0.Win64 DaVinci Resolve Studio 16 Public Beta 2 DesignBuilder 6.1 DICAD Strakon Premium 2019 SP1 DotSoft.C3DTools.v8.0.1.5 DotSoft.MapWorks.v8.0.1.0 E2G.PlantManager.v3.0.1.18956 EngiLab.Beam.2D.Pro.2018.v2.5.6704 Engineered 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HEEDS.MDO.2019.1.0.Win64 IDEA StatiCa 10.0.24 x64 I-GIS GeoScene3D v10.0.13.574 IMSI.TurboCAD.Civil.2017.v24.0.663.Win32_64 IMSI.TurboFloorPlan.3D.Home.and.Landscape.Pro.2019.v20.0 IMSI.TurboFloorPlan.Home.and.Landscape.Deluxe.2019.v20.0 IMSPost.v8.3e.Suite.Win64 InnovMetric.PolyWorks.Metrology.Suite.2018.IR11.1.Win32_64 Integrand EMX 5.5.2 Interface With Cadence Virtuoso IC 06.17.722 Linux64 Intergraph PV Elite 2019 SP1 v21.00.01 Intergraph SmartPlant P&ID 2014 R1 HF3 v07.01.00.0292 ITASCA 3DEC 5.20.277 x64 ITASCA FlAC 8.00.454 x64 ITASCA FLAC3D 6.0.69 x64 ITASCA PFC Suite 6.00.13 x64 JewelSuite 2017 Keysight Model Builder Program (MBP) 2019 x64 Keysight Model Quality Assurance (MQA) 2019 x64 Keysight.Agilent.GoldenGate.2015.01 Killetsoft SEVENPAR v9.0.6 Killetsoft TRANSDAT Professional v22.10 Klokan.MapTiler.Plus.v10.0.24 Korf.Hydraulics.v3.5 LabVIEW NXG 3.1.1 Win64 Lead 3.0 LEAD3.0 LimitState Geo 3.5 x64 LimitState RING 3.2b x64 LimitState SLAB 2.1b LS-DYNA.SMP.R11.0.0 LSS Elite 9.91 MagicTable v1.8 MAGNA.KULI.v13.0 Maplesoft Maple 2019 Fixed FULL MasterCAM 2019 Update 3.1 Materialise Magics RP 23.01 x64 MathWorks.MATLAB.R2019a MedCalc 19.0 Mentor HDL Designer Series 2018.2 Win/Linux Mentor.Graphics.Calibre.2018.4.25.17.Linux Mentor.Graphics.FloEFD.2019.1.0.v4540.Suite Merrick MARS 2019.1 x64 Meteonorm 7.3.1.20860 Metso FactNet 5.0 MicroSurvey.STARNET.Ultimate.v9.1.4.7868 Midas Gen 2019 v2.1 midas.MeshFree.V300.R2 midas.NFX.2018.R2.20190211 MITCalc.v1.74 Mootools 3D Browser 14.25 Mootools Polygon Cruncher 12.25 Motor-CAD.MotorCAD 12.2.1 Movicon 2019 v11.6 Movicon.NExT 2019 v3.4 MSC Nastran 2019 x64 MSC Patran 2019 x64 MSC.ADAMS.V2019 nanoCAD 3DScan 1.0 x64 nanoSoft.nanoCAD.Pro.v10.0.4447.1969.4520 NCG CAM 16.0.10 x64 NI.LabVIEW.NXG.3.0.0 NuHertz Filter Solutions 2019 v16.0 NUMECA.FineMarine.8.1.Win64 NUMECA.FineTurbo.13.2 NUMECA.Omnis.3.1 Optiwave OptiSystem 16.0 x64 Outotec.HSC.Chemistry.v9.5.1.5 Paradigm Geolog 18 PC.SCHEMATIC.Automation.40.v20.0.3.54 PCSWMM 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CP-Studio Crosslight Csuprem 2018 x64 crystal 2018.1 csi preform 3d v6 Cype 2017m Dental Master 2016 Dental Shaper Dental Wings (DWOS) 2016 DENTSPLY Simplant Pro 18.0 DesignBuilder 5.4 Deswik suite 2018.1.294 Digital Smile System 1.9.8 DNV GL AS PHAST DNV Patran-Pre 2018 x64 DNV safty offshore 7.2 DNV Sesam all moduels DNV SESAM FULL 2018 Dolphin Imaging 11.9 DP-moderler ECGLab Holter 12.NET EFI Fiery 6.3.1 EICAD 3 Ekahau Site Survey 8.6.1 em-test expert v8 emtp-rv 3.5 ensilica Xtensa Xplorer 7.0.9 Linux Ensoft LPile 2018.10.02 EnterVol 2017.4 for ArcGis EnterVol for ArcGis ERDAS IMAGINE 2018 Ergosoft PosterPrint Poster Print 14 ErgoSoft RIP 15 Ergosoft TexPrint 2008 13.0 Exocad 2.3 Matera 2019 exocad dentalcad 64bit version 2019-02-20 Exocad Exoplan 2019 Matera 2.3 exocad PartialCAD 2018 EyeRadar 2.0 ez-fixture 9.6.4 ezgrid 9.5 FANUC NC GUIDE V10.0 Faro Scene V7.1 FAROBox PointSense plant 18.5 Fiery XF v6.5 FlexiSIGN & PRINT 12 FlexiSIGN Pro 10.5.1 FlexScan3D v3.3.5.8 framecad 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SmartPlant P&ID 2014 R1 Intergraph SmartPlant Review 2017 v12.00.00.0501 Intergraph SmartPlant Spoolgen Isometrics 2014.v08 Intergraph SmartSketch 2014.v08.00.00 R1 INVIVIO v6 IPM.Petroleum.Expert.v10 ITASCA 3DEC v5.20.250 ITASCA Flac v8.0.443 ITASCA Flac3D V6.0.48 ITASCA Griddle v1.0.1 ITASCA PFC v5.0.32 ITASCA UDEC v6.0.323 JAR reconstrucer 3.3.0 x64 jason 9.7 kepware 5.20 Keysight Genesys 2018 x64 Keysight Model Builder Program (MBP) 2017.2 x64 Keysight Model Quality Assurance (MQA) 2017.2 x64 Leapfrog Geo 4.0 Leapfrog Geothermal 3.2 Leapfrog Hydro 2.6 Leica CloudWorx 2.1.4 For PDMS 12.1 SP4 Leica CloudWorx 2.2 For Revit 2014-2019 Leica CloudWorx 5.1.4 for MicroStation V8i Leica CloudWorx 6.4 for AutoCAD 2015-2019 Leica Cyclone 9.3 x64 Leica Cyclone REGISTER 360 1.5.0 x64 Leica GEOMOS v5.0 LEICA infinity 2.4 Leica MultiWorx 2.3 For AutoCAD 2014-2019 x64 leica patialAnalyzer Leica Xpro 6.4 lighttools 8.6 Maestro 3D Dental Studio 4 Maestro Ortho Studio v3.0 MagiCAD 2018 MAGIX Vegas 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Most searched keywords

Let’s first take a look at what are the most popular keywords that customers have been using when searching for icons on Iconfinder. The table below lists these keywords in order of popularity, from most searched to least.

The column called Supply-Demand ratio shows how competitive the Iconfinder market for that keyword is:

  • A ratio lower than 1 means that there is space for more icons.
  • A ratio higher than 1 means that the market is very competitive — there are more icons than searches for that keyword, so sales are not guaranteed.

The last column shows whether the searches for that keyword have been increasing or decreasing as compared to the same period last year.

It is not surprising to see keywords such as “arrow”, “phone”, “download”, “search” or “user” ranking as the most searched in 2019 so far. These are the basis of UIs and websites and most customers will be looking for these. They are a good place to start if you are new at icon design.

As an icon designer, you are probably asking what are the icons that customers buy together. This is useful information when deciding what icons to include in the same set or the same icon family. To answer this question, we looked at what keywords customers search for successively.

For example, a typical case is to search for “facebook” and then right afterward search for “twitter”. Depending on how many times this exact combination of searches happened, we can intuit how likely it is for a customer to buy the two icons together. Another example of this kind could be a search for “arrow up”, followed by a new search for “arrow down”.

The table below lists the keyword combinations used to search on Iconfinder, from most to least popular. The first keyword is the one that the customer used in the first search. The second keyword is the one the customer used in the second search, immediately after the first one. Most cases are complementary keywords.

This list should be taken with caution, however, as some examples could be interpreted differently. Sometimes, the customer might make a typo and then search for the correct word in the second search. For example, a typo such as “cofee” in the first search would be followed by a second search with the correct spelling of the word: “coffee”.

Synonym keywords — a hint for better tagging

Another very important scenario is when customers cannot find what they are looking for with the first keyword and then try with a second one. This corresponds to words that are synonyms. For example, if you cannot find the right icon using the keyword “remove”, you might try using the word “delete” instead. These are important clues for tagging — they should help you come up with better tags.

Knowing that there were 791 times when people searched for “remove” and then, immediately after, searched for “delete” tells you that those are two very important tags to add to your relevant icons. This way, you help the customers find your icons more easily.

If you need help finding synonyms when tagging, a good idea is to use an external tool such as this one: https://www.powerthesaurus.org/. When uploading icons to Iconfinder, our tagging tool also suggests other tags based on what you enter. Note that the recommended number of tags is between 4 and 7 per icon. Read Iconfinder’s guidelines for tagging.

The process of tagging

Tagging icons is the most important thing that you as a designer can do for your business. It should be an integral part of your design process. It is equally important to get the tags right as it is to create good quality icons.

After you have decided on what the right tags are — hopefully also with the help of our tips above — you need to do tagging in a systematic manner. Read about this in our tutorial How to use artboards export to auto-tag icons.

We looked at what keywords gain popularity in Q4 by looking at the searches in October, November, and December last year. We compared those to the previous 3 months and selected only the keywords that had a large increase in searches.

We noticed mostly searches related to the main festivities during fall and winter: Halloween, Thanksgiving, Christmas, New Year and Diwali. The chart below shows at which time of the year the searches for each type of keyword reach a peak. For a complete list of keywords and their increase in popularity, check the Seasonal trends for keywords in Q4.

Searches per week and month for different keywords in Q4 2018.

Here are some of the seasonal sets that we consider as high quality, which can hopefully inspire you.

For more ideas on what icons to create and when keep an eye on Google Trends. It is a good source of popular topics that people are presently searching for online and a good indicator of what customers are searching for on Iconfinder too.

Here are the campaigns we plan to run in Q4, for which we often promote icons that match the theme of the campaign. We recommend designers to upload the themed icons before the campaign begins, in order to have a chance to be featured.

Here is an example of the Halloween campaign (which is running until the end of October) where we offer discounts on the Iconfider Pro plans. For this campaign, we featured beautifully-drawn Halloween icon sets.

The list below shows the category-style combinations in order of sales, from most sales to least. The best-sellers are Business & Finance in outline, glyph, and flat styles, followed by Avatars & Smileys in flat style, and UI in outline style.

You should pay attention to the last column (Supply-Demand ratio), which shows how saturated the market is in each category-style pair.

  • A ratio lower than 1 means that there is space for more icons.
  • A ratio higher than 1 means that the market is very competitive — there are more icons than searches for that keyword, so sales are not guaranteed.

Note that these category-style pairs are very competitive, so it is important to try to stand out from the crowd and differentiate yourself.

To make this list easier to grasp, we’ve added a few examples of sets that correspond to the category-style pairs from the top of the list.

From the list above, we have selected only those category-style combinations that offer opportunities to add more icons. These are the ones with a supply-demand ratio lower than 1, which means that they sell more icons than the total number of icons available on Iconfinder.

Pay attention, however, to the number of icons sold in each category-style pair. These are not among the top seller ones, which means that you cannot expect that many sales. Yet, creating icons for these is a good idea because there is less competition.

To illustrate what the list means, we are adding a few examples of good sets for the first few category-style pairs.

Here we are listing a few examples of what we consider as bad practices when it comes to designing icons. We take the point of view of the customer by thinking in terms of the usability of the icon.

Directly-converted glyphs

Over the last few months, we have noticed an increase in the popularity of a certain style of glyph icons. It is the practice of creating an outline icon and then inverting it so that it looks like a glyph.

This is an example of what we mean by glyph icons that have been directly converted from their outline versions:

As you can see in the example above, the icons become very difficult to recognize, especially in small sizes. Icons are meant to be used in small sizes, so simply creating a style conversion, without reinterpreting the icons, makes them lose their entire functionality.

Let’s look at a few examples together.

Bad glyph icons (directly-converted)

In all these examples, the designer made a direct style conversion, mostly because it only takes a second to do. However, the icons do not look good and Iconfinder does not accept them anymore.

When designing a glyph icon, the icon needs to be rethought based on the style limitations, making sure that they are easy to understand. Glyph icons are characterized by the use of negative space.

Good glyph icons

In the examples below, the icons are not simply converted directly to glyph. Instead, the designer has paid attention that the concept that the icon represents is still very clear.

Gradients in outline icons

We also noticed a trend of gradients in outline icons. In general, using colors in outline icons needs to be very well thought out. Colors need to play a role in the icon, like highlighting the important parts of the icon itself.

You might think that adding a gradient to an outline icon makes it cool and appealing. In reality, customers will have more trouble if they want to change the color of the icon, as gradients are not so easy to manage, especially for customers with no graphic design knowledge.

In the example below, using a 3-color gradient is definitely not going to make the icons more appealing. Instead, the icons lose their usability, as very few or no customers will want to buy them. Usually, customers look for icons that fit a certain color scheme (their brand’s colors, for instance) and these icons would bring more work for the customers when trying to change the colors.

Remember to always keep the customer in mind when designing icons. We recommend staying away from bad practices — such as directly-converted glyphs and gradients in outline icons — that can ultimately hurt sales.

We hope this report will help you identify the opportunities in the icon market and will inspire you to create beautiful icons.

This report is part of a series that are released every quarter. It crunches data on supply and demand on the Iconfinder marketplace, hoping to lead designers to create the right icons.

Drop us a message at support@iconfinder.com if you have any questions or feedback.

Are you interested in becoming a contributor on Iconfinder? This is the place to start: How to sell icons on Iconfinder

Источник: https://blog.iconfinder.com/iconfinder-designer-report-q4-2019-99c3e5fba587

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